NSTL国家科技图书文献中心

1. Manganese‐Modified Metal Nanoparticle Catalysts for Syngas to C2+‐Oxygenates NSTL国家科技图书文献中心

Jiale Xiao | Haotian Meng ... - 《ChemCatChem》 - 2025,17(4) - n/a～n/a - 共13页

摘要： (i.e., C2+‐oxygenates), is one of the important | , thereby enhancing the yield of C2+‐oxygenates. In this | Abstract Syngas to oxygenates, in particular | promoter are popular candidates for the syngas to C2 | +‐oxygenates, where the Mn effectively optimizes the

关键词： Cobalt | Manganese | Oxygenates | Rhodium | Syngas conversion

2. The Roles of Hydroxyl Radicals and Superoxide in Oxidizing Aqueous Benzyl Alcohol Under Ultrasound Irradiation NSTL国家科技图书文献中心

Ari F. Fischer | Teseer Bahry ... - 《ChemSusChem》 - 2025,18(11) - e202500097～18 - 共18页

摘要： compounds(benzaldehyde and phenol derivatives)and C1-C2 | oxygenates(formic acid, glyoxal, and oxalic acid). Through | acid and C1 oxygenates* via aldehyde and ketone* | The abatement of aromatic pollutants in water | requires their oxidation to nontoxic products by resource

关键词： Advanced oxidation | Conjugate addition | DFT | Radical reactions | Sonochemistry | Sustainable chemistry | Water chemistry

3. Density functional theory study of Cu based catalysts with sulfur modification for the selective conversion of syngas to C2 oxygenates NSTL国家科技图书文献中心

Feng Y. | Zhang J.... - 《Molecular catalysis》 - 2024,559 - 共5页

摘要： oxygenates, and explores the intricate mechanism of C2 | . For C2 oxygenates* formation, the most effective* | enhancing the selectivity to C2 oxygenates. | -modified Cu(100) surface for converting syngas to C2 | oxygenates formation from CO hydrogenation using density

关键词： C2 oxygenates | CO hydrogenation | Cu-based catalyst | Density functional theory | Sulfur

4. Unveiling the Mechanism of Plasma-Catalyzed Oxidation of Methane to C2+ Oxygenates over Cu/UiO-66-NH2 NSTL国家科技图书文献中心

Chong Qi | Yifu Bi ... - 《ACS catalysis》 - 2024,14(10) - 7707～7716 - 共10页

摘要： conversion of CH4 and CO2 into oxygenates* within a* | impressive 53.4% overall liquid selectivity, with C2 | + oxygenates* accounting for -60.8% of the total liquid* | and C2+ liquid formation. This work provides | valuable mechanistic insights into C-C coupling and C2

关键词： plasma catalysis | CH4 oxidation | CO2 conversion | biogas reforming | alcohols | C2+ oxygenates

5. Highly Selective Production of C2+ Oxygenates from CO2 in Strongly Acidic Condition by Rough Ag‐Cu Electrocatalyst NSTL国家科技图书文献中心

Yisen Yang | Jianling Zhang ... - 《Angewandte Chemie》 - 2024,63(47) - n/a～n/a - 共7页

摘要： conversion of CO2 to multi‐carbon (C2+) oxygenates* is of* | selectivity to C2+ oxygenates* can be greatly improved. In a* | + products Faradaic efficiency (FE) and C2+ oxygenates* FE* | C2+ oxygenates* partial current density is as high* | high generation of C2+ oxygenates* over the catalyst*

关键词： acidic electrocatalytic CO2 reduction | multi-carbon oxygenates | ethylene | selectivity | Ag−Cu alloy

6. Enhanced Proximity of Rh1,2‐Rhn Ensembles Encaged in UiO‐67 Boosting Catalytic Conversion of Syngas to Oxygenates NSTL国家科技图书文献中心

Jun Yu | Tingting Liu ... - 《Angewandte Chemie》 - 2024,63(20) - n/a～n/a - 共9页

摘要：; however, the one‐pass yields of C2+ oxygenates* over the* | the one‐pass yield of C2+ oxygenates* exceeded 25* | premise of high oxygenates* selectivity in syngas* | syngas to oxygenates* by precisely tuning the ensemble* | Abstract Maintaining high conversion under the

关键词： Monometallic Rh Catalyst | UiO-67 | Syngas Conversion to Oxygenates | Enhanced Proximity | Dual Active Sites

7. Isolated Ni sites anchored on zeolites for direct synthesis of acetic acid from methane oxidative carbonylation NSTL国家科技图书文献中心

Liu, Jin | Wei, Yao ... - 《Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications》 - 2024,350 - ARTN 123951～ - 共9页

摘要： sites can promote the transformation of CH4 to C2 | + oxygenates* instead of traditional C1 oxygenates as main* | Direct conversion of methane to acetic acid | with high activity and selectivity over non-noble | metal-based catalysts under mild reaction conditions

关键词： Methane | Isolated Ni sites | Acetic acid | Selective oxidation | Zeolite-based catalyst | XPS SPECTRA | METAL | CATALYSTS | CONVERSION | ACTIVATION...

8. A First Principles Mechanistic Study of Higher Alcohol Synthesis from Syngas on a Stepped Rhodium Surface NSTL国家科技图书文献中心

Arevalo, Ryan Lacdao | Nakanishi, Hiroshi - 《Catalysis Letters》 - 2024,154(7) - 3418～3425 - 共8页

摘要：. The formation of C2 oxygenates* toward ethanol* | The mechanism of higher alcohol synthesis (HAS | ) from syngas on a stepped Rhodium surface was explored | using first principles calculations based on density | functional theory. Results showed that the activation of CO

关键词： Higher alcohol synthesis | Rhodium-based catalysts | CO insertion | Density functional theory | GENERALIZED GRADIENT APPROXIMATION | INITIO MOLECULAR-DYNAMICS | DENSITY-FUNCTIONAL THEORY | TOTAL-ENERGY CALCULATIONS | ETHANOL SYNTHESIS | CATALYSTS...

9. Low-Temperature Thermocatalytic Coupling of CH4 and CO2 to Ethanol over Zn-Ce/ZSM-5 by a Stepwise Technique NSTL国家科技图书文献中心

Chaoyu Zhang | Ruijia Wang ... - 《ACS catalysis》 - 2024,14(11) - 8823～8835 - 共13页

摘要： CO2 to C2 oxygenates* at low temperatures has* | Direct thermocatalytic coconversion of CH4 and | attracted extensive attention but is challenged due to | being thermodynamically unfavorable. Herein, we report | the direct coupling of CH4 and CO2 to ethanol as the

关键词： CH4 | CO2 | ethanol | Zn-Ce/ZSM-5 | stepwise reactor

10. Selectivity Control by Relay Catalysis in CO and CO 2 Hydrogenation to Multicarbon Compounds NSTL国家科技图书文献中心

Cheng, Kang | Li, Yubing ... - 《Accounts of Chemical Research》 - 2024,57(5) - 714～725 - 共12页

摘要：, and C2+ oxygenates* from CO/CO2 with selectivity* | CO2 into high-value multicarbon (C2+) compounds | CO/CO2 to C2+ compounds primarily rely on a direct | ., methanol synthesis from CO/CO2 and methanol to C2 | hydrogenation of CO/CO2 to a high-value C2+ compound is one of

关键词： GASOLINE-RANGE HYDROCARBONS | FISCHER-TROPSCH CATALYSTS | LOWER OLEFINS | BIFUNCTIONAL CATALYSTS | DIRECT CONVERSION | LIQUID FUELS | H-ZSM-5-SUPPORTED COBALT | DIMETHYL ETHER | SYNGAS | DESIGN

摘要： (i.e., C2+‐oxygenates), is one of the important | , thereby enhancing the yield of C2+‐oxygenates. In this | Abstract Syngas to oxygenates, in particular | promoter are popular candidates for the syngas to C2 | +‐oxygenates, where the Mn effectively optimizes the

关键词： Cobalt | Manganese | Oxygenates | Rhodium | Syngas conversion

摘要： compounds(benzaldehyde and phenol derivatives)and C1-C2 | oxygenates(formic acid, glyoxal, and oxalic acid). Through | acid and C1 oxygenates via aldehyde and ketone | The abatement of aromatic pollutants in water | requires their oxidation to nontoxic products by resource

关键词： Advanced oxidation | Conjugate addition | DFT | Radical reactions | Sonochemistry | Sustainable chemistry | Water chemistry

摘要： oxygenates, and explores the intricate mechanism of C2 | . For C2 oxygenates formation, the most effective | enhancing the selectivity to C2 oxygenates. | -modified Cu(100) surface for converting syngas to C2 | oxygenates formation from CO hydrogenation using density

关键词： C2 oxygenates | CO hydrogenation | Cu-based catalyst | Density functional theory | Sulfur

摘要： conversion of CH4 and CO2 into oxygenates within a | impressive 53.4% overall liquid selectivity, with C2 | + oxygenates accounting for -60.8% of the total liquid | and C2+ liquid formation. This work provides | valuable mechanistic insights into C-C coupling and C2

关键词： plasma catalysis | CH4 oxidation | CO2 conversion | biogas reforming | alcohols | C2+ oxygenates

摘要： conversion of CO2 to multi‐carbon (C2+) oxygenates is of | selectivity to C2+ oxygenates can be greatly improved. In a | + products Faradaic efficiency (FE) and C2+ oxygenates FE | C2+ oxygenates partial current density is as high | high generation of C2+ oxygenates over the catalyst

关键词： acidic electrocatalytic CO2 reduction | multi-carbon oxygenates | ethylene | selectivity | Ag−Cu alloy

摘要：; however, the one‐pass yields of C2+ oxygenates over the | the one‐pass yield of C2+ oxygenates exceeded 25 | premise of high oxygenates selectivity in syngas | syngas to oxygenates by precisely tuning the ensemble | Abstract Maintaining high conversion under the

关键词： Monometallic Rh Catalyst | UiO-67 | Syngas Conversion to Oxygenates | Enhanced Proximity | Dual Active Sites

摘要： sites can promote the transformation of CH4 to C2 | + oxygenates instead of traditional C1 oxygenates as main | Direct conversion of methane to acetic acid | with high activity and selectivity over non-noble | metal-based catalysts under mild reaction conditions